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JCST

Journal of Current Science and Technology

ISSN 2630-0656 (Online)

Synthesis and characterization of a new copper(II) coordination polymer with mixed ligands of tetrabromoterephthalic acid and imidazole

  • Kodchakorn Samakun, Faculty of Science and Technology, Thammasat University, Pathum Thani, Thailand
  • Chatphorn Theppitak, Faculty of Science and Technology, Thammasat University, Pathum Thani, Thailand
  • Suwadee Jiajaroen, Faculty of Science and Technology, Thammasat University, Pathum Thani, Thailand
  • Winya Dungkaew, Faculty of Science, Mahasarakham University, Mahasarakham, Thailand
  • Taradon Piromchat, Petroleum Authority of Thailand Exploration Production (PTTEP), Bangkok, Thailand
  • Kittipong Chainok, Faculty of Science and Technology, Thammasat University, Pathum Thani, Thailand, Corresponding author; Email: kc@tu.ac.th

Abstract

A new copper(II) coordination polymer containing mixed ligands of tetrabromoterephthalate (Br4tp) and imidazole (Im), [Cu(Br4tp)(Im)(H2O)] (1), was successfully synthesized and characterized by single crystal X-ray diffraction, powder X-ray diffraction, elemental analysis, infrared spectroscopy, and thermogravimetric analysis.  The single crystal X-ray diffraction analysis at 100(2) K and 296(2) K revealed that 1 crystallizes in the centrosymmetric monoclinic with space group C2/c, and displays a two-dimensional sheet with a binodal (3,4)-connected net.  Compound 1 exhibited thermal stability up to 240 °C.

Keywords: coordination polymer, copper(II), crystal structure, imidazole, mixed ligands, thermal decomposition

PDF (1016.29 KB)

DOI: 10.14456/jcst.2019.13

References

Bai, N., Gao, R., Wang, H., Wu, Y., Hou L., & Wang, Y.-Y. (2018). Five transition metal coordination polymers driven by a semirigid trifunctional nicotinic acid ligand: selective adsorption and magnetic properties. CrystEngComm, 20, 5726-5734. DOI: 10.1039/C8CE01003J

Cati, D. S., & Stoeckli-Evans, H. (2014). Crystal structure of poly[[(acetato-κO){μ3-N-[(pyridin-4-yl)meth­yl]pyrazine-2-carboxamidato-κ4N:N1,N2:N4]copper(II)] dihydrate]: a metal–organic framework (MOF). Acta Crystallographica Section C, E70, 23-26. DOI: 10.1107/S1600536814011520

Chainok, K., Ponjan, N., Theppitak, C., Khemthong, P., Kielar, F., Dungkaew, W.,  .  .  . Batten, S. (2018). Temperature-dependent 3D structures of lanthanide coordination polymers based on dicarboxylate mixed ligands. CrystEngComm, 20, 7446-7457. DOI: 10.1039/C8CE01430B

Chongboriboon, N., Samakun, K., Inprasit, T., Dungkeaw, W., Kielar, F., Wong, L. H.-Y.,  .  .  . Chainok, K. (2020). Two-dimensional halogen-bonded organic frameworks based on the tetrabromobenzene-1,4-dicarboxylic acid building molecule. CrystEngComm, 22, 24-34. DOI: 10.1039/C9CE01140D

Duan, J., Zhang, Q., Wang, S., Zhou, B., Sun, J., & Jin, W. (2018). Controlled flexibility of porous coordination polymers by shifting the position of the –CH3 group around coordination sites and their highly efficient gas separation. Inorganic Chemistry Frontiers, 5, 1780-1786. DOI: 10.1039/C8QI00240A

Dungkaew, W., Jiajaroen, S., Theppitak, C., Sertphon, D., & Chainok, K. (2018). Copper (II) adsorption property of 1D coordination polymer [Cu2(H2O)(bipy)2(tp)2] (bipy = 2,2'-bipyridine, tp = terepthalate) after acid treatment. Journal of Current Science and Technology, 9(1), 29-39.

Faustini, M., Nicole L., Ruiz-Hitzky, E., & Sanchez, C. (2018). History of organic–inorganic hybrid materials: prehistory, art, science, and advanced applications. Advanced Functional Materials, 28(27), 1704158-1704188. DOI: 10.1002/adfm.201704158

Inukai, M., Tamura, M., Horike, S., Higuchi, M., Kitagawa, S., & Nakamura, K. (2018). Storage of CO2 into porous coordination polymer controlled by molecular rotor dynamics. Angewandte Chemie, International Edition, 57(28), 8687-8690. DOI: 10.1002/anie.201805111

Li, G., Yang, Q., Pan, R., & Liu, S. (2018). Diverse cobalt (ΙΙ) coordination polymers for water/ethanol separation and luminescence water sensing applications. CrystEngComm, 20, 3891-3897. DOI: 10.1039/C8CE00709H

Li, L., Wang, S., Chen, T., Sun, Z., Luo, J., & Hong, M. (2012). Solvent-dependent formation of Cd(II) coordination polymers based on a C2-symmetric tricarboxylate linker. Crystal Growth & Design, 12(8), 4109-4115. DOI: 10.1021/cg300617h

Li, N., Feng, R., Zhu, J., Chang, Z., & Bu, X.-H. (2018). Conformation versatility of ligands in coordination polymers: From structural diversity to properties and applications. Coordination Chemistry Reviews, 375, 558-586. DOI: doi.org/10.1016/j.ccr.2018.05.016

Lyu, H., Zhang, Q., Wang, Y., & Duan, J. (2018). Unified meso-pores and dense Cu2+ sites in porous coordination polymers for highly efficient gas storage and separation. Dalton Transactions, 47, 4424-4427. DOI: 10.1039/C8DT00512E

Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E.,  .  .  . Wood, P. A. (2008). Mercury CSD 2.0 - new features for the visualization and investigation of crystal structures. Journal of Applied Crystallography, 41(Pt 2), 466-470. DOI: 10.1107/S0021889807067908

Phadungsak, N., Boonyuen, S., Sertphon, D., Dungkeaw, W., Kielar, F., & Chainok, K. (2018). A new three-dimensional zinc(II)–barium(II) coordination polymer based on trimesic acid and imidazole ligands: synthesis, structure and properties. Journal of Current Science and Technology, 8(1), 1-9. DOI: 10.14456/jcst.2018.1

Phadungsak, N., Kielar, F., Dungkaew, W., Sukwattanasinitt, M., Zhou, Y., & Chainok, K. (2019). A new luminescent anionic metal–organic framework based on heterometallic zinc(II)–barium(II) for selective detection of Fe3+ and Cu2+ ions in aqueous solution. Acta Crystallographica Section C, 75(Pt 10), 1372-1380. DOI: 10.1107/S2053229619011987

Razavi, S. A. A., & Morsali, A. (2019). Linker functionalized metal-organic frameworks. Coordination Chemistry Reviews, 399, 213023-213057. DOI: 10.1016/j.ccr.2019.213023

Sheldrick, G. M. (2015a). SHELXT − Integrated space-group and crystal-structure determination. Acta Crystallographica Section A: Foundations and Advances, 71(Pt 1), 3-8. DOI: 10.1107/S2053273314026370

Sheldrick, G. M. (2015b). Crystal structure refinement with SHELXL. Acta Crystallographica, C71, 3-8. DOI: 10.1107/S2053229614024218

Wang, J.-C., Ding, F.-W., Ma, J.-P., Liu, Q.-K., Cheng, J.-Y., & Dong, Y.-B. (2015). Co(II)-MOF: A highly efficient organic oxidation catalyst with open metal sites. Inorganic Chemistry, 54(22), 10865-10872. DOI: 10.1021/acs.inorgchem.5b01938

William, P. L., & Li, J. (2018). Luminescent metal–organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices. Coordination Chemistry Reviews, 373, 116-147. DOI: 10.1016/j.ccr.2017.09.017

Xue, L.-P., Li, Z.-H., Zhang, T., Cui, J.-J., Gaoa, Y., & Yao, J.-X. (2018). Construction of two Zn(II)/Cd(II) multifunctional coordination polymers with mixed ligands for catalytic and sensing properties. New Journal of Chemistry, 42, 14203-14209. DOI: 10.1039/C8NJ02055H

Zhang, Q.-L., Yu, Q., Xie, H.-F., Tu, B., Xu, H., Huang, Y.-L., & Yang, X.-S. (2018). Structural diversity of six coordination polymers based on the designed X-shaped ligand 1,1,1,1-tetrakis[(3-pyridiniourea)methyl]methane. Molecules, 23(9), 2292-2305. DOI: 10.3390/molecules23092292

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