Solvothermal synthesis, structure, and luminescent properties of a series of 3D lanthanide carbonate frameworks
- Phailyn Khemthong, Department of Chemistry, Faculty of Science, Naresuan University, Muang, Phitsanulok, Thailand
- Filip Kielar, Department of Chemistry, Faculty of Science, Naresuan University, Muang, Phitsanulok, Thailand
- Kittipong Chainok, Department of Physics, Faculty of Science and Technology, Thammasat University, Rangsit Campus, Khlong Luang, Patum Thani, Thailand, Corresponding author; E-mail: kc@tu.ac.th
Abstract
A series of three-dimensional (3D) lanthanide carbonate coordination polymers [Ln(μ5-CO3)(μ2-OH)], LnIII = Pr (1Pr), Nd (2Nd), Sm (3Sm), Eu (4Eu), Gd (5Gd), Tb (6Tb) and Dy (7Dy), has been synthesized using solvothermal conditions and characterized by spectroscopic methods. Structures of compounds 1Pr-3Sm were solved from single crystal X-ray diffraction (SCXRD) data, whereas microcrystals of compounds 4Eu-7Dy were not of sufficient quality for SCXRD analysis. Therefore, conventional powder X-ray diffraction (PXRD) and elemental analysis have been used to verify the phase purity. SCXRD analysis revealed that compounds 1Pr-3Sm are isostructural and crystallize in the orthorhombic space group Pnma with four formula units per unit cell. In the crystal structure, each LnIII cation is bridged by five μ5-η2:η2:η2:η1:η1-CO32− and two μ2-OH− ligands forming a neutral 3D framework. The luminescence properties of compounds 4Eu and 6Tb were investigated in the solid state at room temperature.
Keywords: carbonate; crystallography; crystal structure; lanthanide; luminescence; solvothermal synthesis
DOI: 10.14456/rjas.1474.1
References
Andrews, P. C., Beck, T., Forsyth, C. M., Fraser, B. H., Junk, P. C., Massi, M., & Roesky, P. W. (2007). Templated assembly of a µ6-CO32− dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate. Dalton Transactions, Issue 48, 5651-5654. DOI: 10.1039/B710534G
Bag, P., Dutta, S., Biswas, P., Maji, S. K., Flörke, U., & Nag, K. (2012). Fixation of carbon dioxide by macrocyclic lanthanide(III) complexes under neutral conditions producing self-assembled trimeric carbonato-bridged compounds with µ3-η2:η2:η2 bonding. Dalton Transactions, Issue 41, 3414-3423. DOI: 10.1039/C2DT12221A
Bruker (2014). APEX2, SAINT, XPREP and SADABS. Madison, Wisconsin, USA: Bruker AXS Inc.
Bünzli, J.-C. G., & Piguet, C. (2005). Taking advantage of luminescent lanthanide ions. Chemical Society Reviews, 34, 1048-1077. DOI: 10.1039/B406082M
Calvez, G., Daiguebonne, C., & Guillou, O. (2011). Unprecedented lanthanide-containing coordination polymers constructed from hexanuclear molecular building blocks: {[Ln6O(OH)8](NO3)2(bdc)(Hbdc)2·2NO3·H2bdc}∞. Inorganic Chemistry, 50(7), 2851-2858. DOI: 10.1021/ic102036q
Chesman, A. S. R., Turner, D. R., Moubaraki, B., Murray, K. S., Deacon, G. B., & Batten, S. R. (2012). Tetradecanuclear polycarbonatolanthanoid clusters: diverse coordination modes of carbonate providing access to novel core geometries. Dalton Transactions, Issue 41, 10903-10909. DOI: 10.1039/C2DT31101A
Dang, S., Zhang, J. H., Sun, Z. M., & Zhang, H. (2012). Luminescent lanthanide metal-organic frameworks with a large SHG response. Chemical Communications, 48(90), 11139-11141. DOI: 10.1039/C2CC35432B
Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., & Puschmann, H. (2009). OLEX2: a complete structure solution, refinement and analysis program. Journal of Applied Crystallography, 42(2), 339-341. DOI: 10.1107/S0021889808042726
Fang, X., Anderson, T. M., Neiwert, W. A., & Hill, C. L. (2003). Yttrium polyoxometalates: synthesis and characterization of a carbonate-encapsulated sandwich-type complex. Inorganic Chemistry, 42(26), 8600-8602. DOI: 10.1021/ic0350842
Gass, I. A., Moubaraki, B., Langley, S. K., Batten, S. R., & Murray, K. S. (2012). A π–π 3D network of tetranuclear μ2/μ3-carbonato Dy(III) bis-pyrazolylpyridine clusters showing single molecule magnetism features. Chemical Communications, 48(15), 2089-2091. DOI: 10.1039/C2CC16946K
Gu, J. Z., Wu, J., Lv, D. Y., Tang, Y., Zhu, K., & Wu, J. (2013). Lanthanide coordination polymers based on 5-(2′-carboxylphenyl) nicotinate: syntheses, structure diversity, dehydration/hydration, luminescence and magnetic properties. Dalton Transactions, Issue 42, 4822-4830. DOI: 10.1039/C2DT32674D
Gunanathan, C., Diskin-Posner, Y., &Milstein, D. (2010). Lanthanide-organic framework of a rigid bis-Gd complex: composed by carbonate ions spacers. Crystal Growth and Design, 10(10), 4235-4239. DOI: 10.1021/cg100843k
Guo, Z., Song, X., Lei, H., Wang, H., Su, S., Xu, H., . . . Chen, B. (2015). A ketone functionalized luminescent terbium metal-organic framework for sensing of small molecules. Chemical Communications, 51, 376-379. DOI: 10.1039/C4CC06729K
Han, J. W., & Hill, C. L. (2007). A coordination network that catalyzes O2-based oxidations. Journal of the American Chemical Society, 129(49), 15094-15095. DOI: 10.1021/ja069319v
Hooper, T. N., Inglis, R., Palacios, M. A., Nichol, G. S., Pitak, M. B., Coles, S. J., . . . Brechin, E. K. (2014). CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron. Chemical Communications, 50(26), 3498-3500. DOI: 10.1039/C4CC00141A
Hutchings, A.-J., Habib, F., Holmberg, R. J., Korobkov, I., & Murugesu, M. (2014). Structural rearrangement through lanthanide contraction in dinuclear complexes. Inorganic Chemistry, 53(4), 2102-2112. DOI: 10.1021/ic402682r
Langley, S. K., Moubaraki, B., & Murray, K. S. (2012). Magnetic properties of hexanuclear lanthanide(III) clusters incorporating a central μ6-carbonate ligand derived from atmospheric CO2 fixation. Inorganic Chemistry, 51(7), 3947-3949. DOI: 10.1021/ic3002724
Langley, S. K., Chilton, N. F., Moubaraki, B., & Murray, K. S. (2013). Anisotropy barrier enhancement via ligand substitution in tetranuclear {CoIII2LnIII2} single molecule magnets. Chemical Communications, 49(62), 6965-6967. DOI: 10.1039/C3CC44037K
Langley, S. K., Wielechowski, D. P., Vieru, V., Chilton, N. F., Moubaraki, B., Chibotaru, L. F., & Murray, K. S. (2014). Modulation of slow magnetic relaxation by tuning magnetic exchange in {Cr2Dy2} single molecule magnets. Chemical Science, 5, 3246-3256. DOI: 10.1039/C4SC01239A
Langley, S. K., Wielechowski, D. P., Vieru, V., Chilton, N. F., Moubaraki, B., Chibotaru, L. F., & Murray, K. S. (2015). The first 4d/4f single-molecule magnet containing a {RuIII2DyIII2} core. Chemical Communications, 51, 2044-2047. DOI: 10.1039/C4CC08811E
Li, Y. F., Jin, L., Li, D. P., & Zhang, L. (2008). NdO(NO3). Acta Crystallographica Section E: Structure Reports Online, E64, i81. DOI: 10.1107/S1600536808036295
Li, Q. Y., Yang, G. W., Tang, X. Y., Ma, Y. S., Yao, W., Zhou, F., . . . Zhou, H. (2010). Constructions of a set of new lanthanide-based coordination polymers with Hatza Ligands (Hatza = 5-aminotetrazole-1-acetic acid). Crystal Growth and Design, 10(1), 165-170. DOI: 10.1021/cg900807t
Long, D. L., Blake, A. J., Champness, N. R., Wilson, C., & Schröder, M. (2001). Unprecedented seven- and eight-connected lanthanide coordination networks. Angewandte Chemie International Edition, 40(13), 2443-2447. DOI: 10.1002/1521-3773(20010702)40:13<2443::AID-ANIE2443>3.0.CO;2-C
Long, D. L., Blake, A. J., Champness, N. R., Wilson, C., & Schröder, M. (2002). Constructing terbium coordination polymers of 4,4′-bipyridine-N,N′-dioxide by means of diffusion solvent mixtures. Chemistry – A European Journal, 8(9), 2026-2033. DOI: 10.1002/1521-3765(20020503)8:9<2026::AID-CHEM2026>3.0.CO;2-8
Long, J., Rouquette, J., Thibaud, J. M., Ferreira, R. A. S., Carlos, L. D., Donnadieu, B., . . . Larionova, J. (2015). A high-temperature molecular ferroelectric Zn/Dy complex exhibiting single-ion-magnet behavior and lanthanide luminescence. Angewandte Chemie International Edition, 127(7), 2236-2240. DOI: 10.1002/ange.201410523
Lu, W. G., Jiang, L., & Lu, T. B. (2010). Lanthanide contraction and temperature-dependent structures of lanthanide coordination polymers with imidazole-4,5-dicarboxylate and oxalate. Crystal Growth and Design, 10(10), 4310-4318. DOI: 10.1021/cg100196j
Ma, X., Li, X., Cha, Y. E., & Jin, L. P. (2012). Highly thermostable one-dimensional lanthanide(III) coordination polymers constructed from benzimidazole-5,6-dicarboxylic acid and 1,10-phenanthroline: synthesis, structure, and tunable white-light emission. Crystal Growth and Design, 12(11), 5227-5232. DOI: 10.1021/cg300932a
Marchal, C., Filinchuk, Y., Chen, X. Y., Imbert, D., & Mazzanti, M. (2009). Lanthanide-based coordination polymers assembled by a flexible multidentate linker: design, structure, photophysical properties, and dynamic solid-state behavior. Chemistry – A European Journal, 15(21), 5273-5288. DOI: 10.1002/chem.200802589
Martínez-Calvo, M., Kotova, O., Möbius, M. E., Bell, A. P., McCabe, T., Boland, J. J., & Gunnlaugsson, T. (2015). Healable luminescent self-assembly supramolecular metallogels possessing lanthanide (Eu/Tb) dependent rheological and morphological properties. Journal of the American Chemical Society, 137(5), 1983-1992. DOI: 10.1021/ja511799n
Matthes, P. R., Nitsch, J., Kuzmanoski, A., Feldmann, C., Steffen, A., Marder, T. B., & Müller-Buschbaum, K. (2013). The series of rare earth complexes [Ln2Cl6(μ-4,4′-bipy)(py)6], Ln=Y, Pr, Nd, Sm-Yb: A molecular model system for luminescence properties in MOFs based on LnCl3 and 4,4′ bipyridine. Chemistry – A European Journal, 19(51), 17369-17378. DOI: 10.1002/chem.201302504
Mcmahon, B., Mauer, P., Mccoy, C. P., Lee, T C., & Gunnlaugsson, T. (2009). Selective imaging of damaged bone structure (microcracks) using a targeting supramolecular Eu(III) complex as a lanthanide luminescent contrast agent. Journal of the American Chemical Society, 131(48), 17542-17543. DOI: 10.1021/ja908006r
Mishra, A., Wernsdorfer, W., Abboud, K. A., & Christou, G. (2004). Initial observation of magnetization hysteresis and quantum tunneling in mixed manganese-lanthanide single-molecule magnets. Journal of the American Chemical Society, 126(48), 15648-15649. DOI: 10.1021/ja0452727
Mu, W., Huang, X., Zhong, R., Xia, W., Liu, J., & Zou, R. (2015). Lanthanide contraction effects on the structures, thermostabilities, and CO2 adsorption and separation behaviors of isostructural lanthanide-organic frameworks. CrystEngCommunity, 17(7), 1637-1645. DOI: 10.1039/C4CE02073A
Nakai, H., Goto, T., Kitagawa, K., Nonaka, K., Matsumoto, T., & Ogo, S. (2014). A highly luminescent and highly oxygen-sensitive Tb(III) complex with a tris-aryloxide functionalised 1,4,7 triazacyclononane ligand. Chemical Communications, 50, 15737-15739. DOI: 10.1039/C4CC07717B
Okamoto, Y. (2002). Organo lanthanide metal complexes for electroluminescent materials. Chemical Reviews, 102(6), 2357-2368. DOI: 10.1021/cr010448y
Regueiro-Figueroa, M., Esteban-Gómez, D., de Blas, A., Rodríguez-Blas, T., & Platas-Iglesias, C. (2014). Understanding stability trends along the lanthanide series. Chemistry – A European Journal, 20(14), 3974-3981. DOI: 10.1002/chem.201304469
Sastri, V. S., Bünzli, J.-C. G., Rao, V. R., Rayudu, G. V. S., & Perumareddi, J. R. (2003). In Modern Aspects of Rare Earth and Their Complexes. New York, USA: Elsevier.
Seidel, C., Lorbeer, C., Cybińska, J., Mudring, A. V., & Ruschewitz, U. (2012). Lanthanide coordination polymers with tetrafluoroterephthalate as a bridging ligand: thermal and optical properties. Inorganic Chemistry, 51(8), 4679-4688. DOI: 10.1021/ic202655d
Sheldrick, G. M. (2015). Crystal structure refinement with SHELXL. Acta Crystallographica Section C: Crystal Structure Communications, C71, 3-8. DOI:10.1107/S2053229614024218
Sheu, H. S., Shih, W. J., Chuang, W. T., Li, I. F., & Yeh, C. S. (2010). Crystal structure and phase transitions of Gd(CO3)OH studied by synchrotron powder diffraction. Journal of the Chinese Chemical Society, 57(4B), 938-945. DOI: 10.1002/jccs.201000130
Sivakumar, S., Reddy, M. L. P., Cowley, A. H., & Butorac, R. R. (2011). Lanthanide-based coordination polymers assembled from derivatives of 3,5-dihydroxy benzoates: syntheses, crystal structures, and photophysical properties. Inorganic Chemistry, 50(11), 4882-4891. DOI: 10.1021/ic2001249
Sun, J., Kyotani, T., & Tomita, A. (1986). Preparation and characterization of lanthanum carbonate hydroxide. Journal of Solid State Chemistry, 65(1), 94-99. DOI: 10.1016/0022-4596(86)90093-9
Wang, C. G., Xing, Y. H., Li, Z. P., Li, J., Zeng, X. Q., Ge, M. F., & Niu, S. Y. (2009). A series of three-dimensional lanthanide-rigid-flexible frameworks: synthesis, structure, and luminescent properties of coordination polymers with 2,5-pyridine dicarboxylic acid and adipic acid. Crystal Growth and Design, 9(3), 1525-1530. DOI: 10.1021/cg801157k
Xu, Y., Ding, S. H., Feng, W. J., Zhou, G. P., & Liu, Y. G. (2006). Samarium(III) carbonate hydroxide. Acta Crystallographica Section E: Structure Reports Online, E62, i147-i149. DOI: 10.1107/S1600536806022665
Xu, W., Zhou, Y., Huang, D., Xiong, W., Su, M., Wang, K., Han, S., & Hong, M. (2013). Crystal structure, multiplex photoluminescence, and magnetic properties of a series of lanthanide coordination polymers based on quinoline carboxylate ligand. Crystal Growth and Design, 13(13), 5420-5432. DOI: 10.1021/cg401391b
Yan, X., Li, Y., Wang, Q., Huang, X., Zhang, Y., Gao, C., . . . Shao, Y. (2011). Two- to one-dimensional: radii-dependent self-assembly crystal structures and luminescent properties of lanthanide coordination polymers with an amide type semirigid bridging ligand. Crystal Growth and Design, 11(9), 4205-4212. DOI: 10.1021/cg200816f
Zhang, J., Zheng, B., Zhao, T., Li, G., Huo, Q., & Liu, Y. (2014). Topological diversities and luminescent properties of lanthanide metal-organic frameworks based on a tetracarboxylate ligand. Crystal Growth and Design, 14(5), 2394-2400. DOI: 10.1021/cg500114k
Zhang, Y., Huang, L., Miao, H., Wan, H. X., Mei, H., Liu, Y., & Xu, Y. (2015). Hydrothermal synthesis, structure, and optical properties of two nanosized Ln26@CO3 (Ln = Dy and Tb) cluster-based lanthanide-transition-metal-organic frameworks (Ln MOFs). Chemistry – A European Journal, 21(8), 3234-3241. DOI: 10.1002/chem.201405178
Zhao, B., Chen, X. Y., Cheng, P., Liao, D. Z., Yan, S. P., & Jiang, Z. H. (2004). Coordination polymers containing 1D channels as selective luminescent probes. Journal of the American Chemical Society, 126(47), 15394-15395. DOI: 10.1021/ja047141b

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